Alumina
Author's
Note: In my career as
an underwriter and adjuster, I kept notes of my experience with various
cargoes
including information gathered from various sources on different dates
(and hence not always current). While I cannot always guarantee
accurancy of the information, these
notes hopefully would inspire the underwriters to
make further enquiries from their customers before writing the risk.
Your
comments and feedback would enable me to refine and edit these notes. Do
share your experience!
Bauxite is an ore
but Alumina is an intermediate product (refined). Both are relatively easy to
carry and do not shift. The moisture ranges between 0 to 10%. Mainly shipped
from Australia-Bauxite is more internally traded in Australia but Alumina is
exported.
Exported from the
ports of Kwinana which is the outer port, Freemantle being the main port and
Banberry in Western Australia. Here the quantity is determined not on
shore scale but on the basis of draught survey which is reliable in fair
weather if properly done by an experienced surveyor.
Dry Weight versus
Wet Weight
Alumina can be
exported either as dry alumina or wet alumina. If wet, water is sprayed
but sale contract should normally be on the basis of dry weights so that any
water in the bilges and pumped out do not enter the shortage calculation. Wet
Alumina is sold, in other words, on dry weight basis. Insurers should be aware
of this.
Risk of
Shortage
Like in the case of
any bulk cargoes, a deductible is a must-0.50% to 0.75% depending on
the port of loading and/or discharge. Use of vacuators is fine but some ports
use gantry crane and estimated to lose 2 to 3% of cargo due to blowing
everywhere. A draught survey at both ends by a reputed firm of surveyor is a
must as in the case of any other bulk cargo.
Risk of contamination
Alumina requires the hold to
be washed and dried and as it is sensitive to contamination from residues of
previous cargoes, rust (loose/hard rust, flakes etc) which is not
always easy to remove. All exporters generally
arrange hold washing and drying.
It is important fo find out
what agreements have been reached between the buyer and the seller regarding
rust etc Some contracts say “no rust whatsoever.”
Usually
shippers/charterers arrange surveys (survey of the holds, cargo loadiing,
draught reading etc) and in Australia, the quality of surveys and controls are
very good. This also means that the assured would resist another surveyor to be
appointed at the request of cargo insurers.
Cleanliness is required
upto grain standard. It is believed that there have been huge claims in USA(
which accounts for 70% of Alumina imports) due to contamination of alumina.
Effect
of Water (fresh/rain or sea) on Aluimina
There are several grades of
Alumina exported. Some experts say,
depending on the grade involved, sea water may change the chemical
composition of the product. However generally speaking Alumina does not appear
to be sensitive to water (in fact alumina is loaded during rains though
the charterer would obtain a guarantee certificate against claim for wet damage
at disport.)
I had occasion to consult a Chemist in London
regarding the effect of water (salt or fresh) on Metallurgical Grade Calcined
Sandy Alumina used by Aluminium smelters. The response received was :
“In theory alumina, aluminium oxide is chemically inert and insoluble in water. This sort of data is available from any standard MSDS. However if you go a bit deeper, then you start to find papers on the hydration of aluminium oxide and research items demonstrating surface reactions involving water and aluminium oxide (Science.Vol.282.No5387, 0 October 1998). I've looked further into this and regret that there is not much info available. My previous comments stand, it is described as unreactive but I think that it can be hydrated and that's about all."
What does happen in case of wet damage to alumina is that the wetted material dries into a cake which might then need further processing. Certainly wet alumina is described as a difficult material to handle. Particles in suspension are very small.
“In theory alumina, aluminium oxide is chemically inert and insoluble in water. This sort of data is available from any standard MSDS. However if you go a bit deeper, then you start to find papers on the hydration of aluminium oxide and research items demonstrating surface reactions involving water and aluminium oxide (Science.Vol.282.No5387, 0 October 1998). I've looked further into this and regret that there is not much info available. My previous comments stand, it is described as unreactive but I think that it can be hydrated and that's about all."
What does happen in case of wet damage to alumina is that the wetted material dries into a cake which might then need further processing. Certainly wet alumina is described as a difficult material to handle. Particles in suspension are very small.
Since the only
people who really know the answer to this are the users such as Aluminium Metal
producers, a leading manufacturer was contacted. Their reply was
“ We need alumina which have a maximum of 0.8% moisture for the process to get best results - they engage a contractor for drying and crushing the lumps. There would not be any chemical effect on the material but handling of lumps (i.e not free flowing) including loading/unloading from railway wagons becomes difficult and with greater moisture would have process related problems especially in the pot due to temperature variations/ moisture.”
Often in the case of bulk cargoes, small quantities of dried cargo is mixed with larger quantity of sound cargo as a mechanism to mitigate the loss
“ We need alumina which have a maximum of 0.8% moisture for the process to get best results - they engage a contractor for drying and crushing the lumps. There would not be any chemical effect on the material but handling of lumps (i.e not free flowing) including loading/unloading from railway wagons becomes difficult and with greater moisture would have process related problems especially in the pot due to temperature variations/ moisture.”
Often in the case of bulk cargoes, small quantities of dried cargo is mixed with larger quantity of sound cargo as a mechanism to mitigate the loss

Good write up, Vish. Very educative.
ReplyDeleteHave also share it on the India Insurance Forum Blog.
Thanks.
Best wishes,
Anish Jacob Vadakkedath
Anish, thanks a lot.Why dont you contribute something to the blog-you have a wide and rich experience too? Kind Regards.Vish
ReplyDelete